the information by dmzalarm is correct.
although the gmail chat is also google talk, this one is work via HTTP/HTTPS, so it's monitored by the HTTP Proxy.
the standalone client of google talk (and any other XMPP client) can be monitored via IM/P2P Security >> Instant Messaging >> Protocols (so IM/P2P Classifier is the correct log file to checkout what's going on).
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Sascha Rudolph ~ Senior Software Developer ~ Astaro AG
GPG Key Fingerprint: E4BC 501C 0B97 D89E CBE3 9AE5 E321 B8A1 2013 1B78
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